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• W2264291258 abstract "Abstract Treatment of ( CH 3 CN ) 3 Mo ( CO ) 3 with the trimetaphosphate salt [ PPN ] 3 [ P 3 O 9 ] · H 2 O ( [ PPN ] + = [ Ph 3 P N- PPh 3 ] + ) (acetonitrile, 25 ° C ) gave the trimetaphosphate-molybdenum complex [ ( P 3 O 9 ) Mo ( CO ) 3 ] 3 - in 91% isolated yield. [ PPN ] 3 [ ( P 3 O 9 ) Mo ( CO ) 3 ] was also obtained in 77% isolated yield by directly treating Mo ( CO ) 6 with [ PPN ] 3 [ P 3 O 9 ] · H 2 O in refluxing acetonitrile, presumably by generating ( CH 3 CN ) 3 Mo ( CO ) 3 in situ. Reported herein is the full characterization and structural determination of [ PPN ] 3 [ ( P 3 O 9 ) Mo ( CO ) 3 ]  and comparison to synthesized and calculated [ ( P 3 O 9 ) M ( CO ) 3 ] n - (M = group 6–9) complexes." @default.
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• W2264291258 date "2012-03-01" @default.
• W2264291258 modified "2023-09-26" @default.
• W2264291258 title "Synthesis and characterization of the trimetaphosphate molybdenum tricarbonyl anion as its tris(bis(triphenylphosphine)iminium) salt" @default.
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• W2264291258 doi "https://doi.org/10.1016/j.ica.2011.11.060" @default.
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