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- W2264348541 abstract "The synthesis of the iron-nickel clusters (Fe/sub 5/NiC(CO)/sub 15/)/sup 2 -/ and (HFe/sub 3/Ni(CO)/sub 12/)/sup -/ by reacting the carbonyl-containing complexes of iron Fe(CO)/sub 5/), (Fe/sub 5/C(CO)/sub 14/)/sup 2 -/, and (Fe/sub 6/C(CO)/sub 10/)/sup 2 -/ with nickel chloride, which undergoes reduction and carbonylation and participates in the cluster-formation process, has been examined. The variation of the direction of the oxidation of the cluster (Fe/sub 5/NiC(CO)/sub 15/)/sup 2 -/ as a function of the conditions under which it is carried out, where either elimination of the heteroatom, i.e., (Fe/sub 5/NiC(CO)/sub 15/)/sup 2 -/ ..-->.. Fe/sub 5/C(CO)/sub 15/, or its retention in the cluster skeleton, i.e., (Fe/sub 5/NiC(CO)/sub 15/)/sup 2 -/ ..-->.. Fe/sub 5/NiC(CO)/sub 16/, as a result of the replacement of two electrons by a CO molecule liberated upon the partial decomposition of the original cluster is observed, has been investigated. The possibility of the replacement of one heteroatom in a cluster polyhedron by another heteroatom with maintenance of the main cluster-forming element Fe has also been demonstrated for the first time in the example of the reaction of (Fe/sub 5/NiC(CO)/sub 15/)/sup 2 -/ with (Rh(CO)/sub 2/Cl)/sub 2/." @default.
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- W2264348541 date "1987-02-01" @default.
- W2264348541 modified "2023-09-23" @default.
- W2264348541 title "Chemistry of heterometallic carbidocarbonyl clusters. Synthesis and oxidation of the cluster (octahedro-Fe/sub 5/Ni(. mu. /sub 6//sup in/-C)(CO)/sub 15/)/sup 2 -/" @default.
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