FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2265590462> ?p ?o ?g. }

• W2265590462 endingPage "1871" @default.
• W2265590462 startingPage "1861" @default.
• W2265590462 abstract "In the absence/presence of S8, the one-pot assembly of [Et4N][Tp*WS3] [1; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate] with [Cu(MeCN)4]PF6 and bis- or tetraphosphine ligands 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), 1,4-bis(diphenylphosphino)butane (dppb), and N,N,N′,N′-tetrakis(diphenylphosphinomethyl)ethylenediamine (dppeda) produces six W–Cu–S clusters, namely, [(Tp*WS3Cu2Cl)2(dppe)] (2), [Tp*WS3Cu4(dppp)2(μ4-Cl)(μ-Cl)]PF6·MeCN (3·MeCN), [(Tp*WS3Cu3)2(μ4-Cl)(μ-Cl)2(dpppS2)] (4), [(Tp*WS3Cu2Cl)2(dppbS2)]·2MeCN·2H2O (5·2MeCN·2H2O), [(Tp*WS3Cu3Cl2)2(dppbS2)] (6), and [(Tp*WS3Cu3)2(Ph2PS2)3(μ6-Cl)0.5](PF6)0.5·0.75CH2Cl2 (7·0.75CH2Cl2). Compounds 2–7 are characterized by elemental analysis, IR, UV–vis, 1H and 31P{1H} NMR, electrospray ionization mass spectrometry, and X-ray crystallography. For 2, the dppe ligand bridges a pair of butterfly-shaped [Tp*WS3Cu2] cores to form a double-butterfly-shaped structure. For 4, the dppp ligand is susceptible toward S association and forms an in situ generated dpppS2 ligand, supporting an octanuclear double-half-open-cubane structure and contrasting an analogous system wherein a pentanuclear motorcycle-shaped cationic cluster 3 is formed with the absence of S8. A longer dppb ligand readily converts to S-based ligands in 5 and 6, subsequently serving as bridges between a pair of a butterfly-shaped (5) and nest-shaped (6) clusters. Further use of a tetraphosphine ligand, dppeda, in the cluster formation, with the presence of S8, leads to an unexpected ligand degradation to give the [Ph2PS2]− anions. Three [Ph2PS2]− anions juxtapose a pair of nest-shaped cluster cores to yield an octanuclear cluster, 7, featuring a cage to encapsulate μ6-Cl–. The third-order nonlinear-optical (NLO) properties of 2–7 in N,N-dimethylformamide, investigated using a Z-scan technique at 532 nm, show that 2–6 have a reverse saturable absorption, while 7 has a notable saturable absorption. All of 2–7 exhibit a self-focusing effect with hyperpolarizability γ values in the range of 4.71 × 10–30–1.02 × 10–29 esu, which are 440–1000 times higher than that of 1. The formation of 4–7 from 1 through the in situ thiolation of phosphine ligands presents a new approach to the design and assembly of the W–Cu–S clusters with interesting structural arrays and better NLO properties." @default.
• W2265590462 created "2016-06-24" @default.
• W2265590462 creator A5000238995 @default.
• W2265590462 creator A5004196762 @default.
• W2265590462 creator A5007184857 @default.
• W2265590462 creator A5055900883 @default.
• W2265590462 creator A5057645313 @default.
• W2265590462 creator A5060107207 @default.
• W2265590462 creator A5082349825 @default.
• W2265590462 creator A5085485779 @default.
• W2265590462 date "2016-01-26" @default.
• W2265590462 modified "2023-10-16" @default.
• W2265590462 title "Diverse Tp*-Capped W–Cu–S Clusters from One-Pot Assembly Involving in Situ Thiolation of Phosphines" @default.
• W2265590462 cites W1947680280 @default.
• W2265590462 cites W1969802570 @default.
• W2265590462 cites W1970282528 @default.
• W2265590462 cites W1970805862 @default.
• W2265590462 cites W1973458202 @default.
• W2265590462 cites W1974013063 @default.
• W2265590462 cites W1978786371 @default.
• W2265590462 cites W1979183874 @default.
• W2265590462 cites W1983614013 @default.
• W2265590462 cites W1988155151 @default.
• W2265590462 cites W1988333374 @default.
• W2265590462 cites W1991180369 @default.
• W2265590462 cites W1991242720 @default.
• W2265590462 cites W1993814327 @default.
• W2265590462 cites W1993837553 @default.
• W2265590462 cites W1997509165 @default.
• W2265590462 cites W2002561911 @default.
• W2265590462 cites W2004024807 @default.
• W2265590462 cites W2004549769 @default.
• W2265590462 cites W2005773191 @default.
• W2265590462 cites W2011004017 @default.
• W2265590462 cites W2011994941 @default.
• W2265590462 cites W2017213243 @default.
• W2265590462 cites W2018343804 @default.
• W2265590462 cites W2020536613 @default.
• W2265590462 cites W2021653294 @default.
• W2265590462 cites W2022081593 @default.
• W2265590462 cites W2022347265 @default.
• W2265590462 cites W2023060335 @default.
• W2265590462 cites W2024361772 @default.
• W2265590462 cites W2025070574 @default.
• W2265590462 cites W2025139827 @default.
• W2265590462 cites W2027372701 @default.
• W2265590462 cites W2029143651 @default.
• W2265590462 cites W2029405730 @default.
• W2265590462 cites W2033874373 @default.
• W2265590462 cites W2033965639 @default.
• W2265590462 cites W2037382852 @default.
• W2265590462 cites W2038386569 @default.
• W2265590462 cites W2045956682 @default.
• W2265590462 cites W2050403736 @default.
• W2265590462 cites W2051385840 @default.
• W2265590462 cites W2052294696 @default.
• W2265590462 cites W2053938578 @default.
• W2265590462 cites W2054444190 @default.
• W2265590462 cites W2056498189 @default.
• W2265590462 cites W2058892543 @default.
• W2265590462 cites W2062549957 @default.
• W2265590462 cites W2063334178 @default.
• W2265590462 cites W2063443513 @default.
• W2265590462 cites W2064522140 @default.
• W2265590462 cites W2067723282 @default.
• W2265590462 cites W2069005428 @default.
• W2265590462 cites W2069233782 @default.
• W2265590462 cites W2073802762 @default.
• W2265590462 cites W2074767158 @default.
• W2265590462 cites W2078322101 @default.
• W2265590462 cites W2081260989 @default.
• W2265590462 cites W2085959574 @default.
• W2265590462 cites W2089465920 @default.
• W2265590462 cites W2090257479 @default.
• W2265590462 cites W2103539244 @default.
• W2265590462 cites W2106280766 @default.
• W2265590462 cites W2117206348 @default.
• W2265590462 cites W2118421135 @default.
• W2265590462 cites W2122653107 @default.
• W2265590462 cites W2125771483 @default.
• W2265590462 cites W2130291693 @default.
• W2265590462 cites W2132454074 @default.
• W2265590462 cites W2142145843 @default.
• W2265590462 cites W2145818582 @default.
• W2265590462 cites W2150803577 @default.
• W2265590462 cites W2162247258 @default.
• W2265590462 cites W2163150456 @default.
• W2265590462 cites W2164110657 @default.
• W2265590462 cites W2164550923 @default.
• W2265590462 cites W2166689829 @default.
• W2265590462 cites W2168443501 @default.
• W2265590462 cites W2209631265 @default.
• W2265590462 cites W2235653256 @default.
• W2265590462 cites W2239110165 @default.
• W2265590462 cites W2317537730 @default.
• W2265590462 cites W2320704837 @default.
• W2265590462 cites W2324237069 @default.
• W2265590462 cites W2326318157 @default.

• next