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• W2265933462 abstract "Temperature measurements ranging from a few degrees to a few hundreds of Kelvin are of great interest in the fields of nanomedicine and nanotechnology. Here, we report a new ratiometric luminescent thermometer using thermally excited state absorption of the Eu(3+) ion. The thermometer is based on the simple Eu(3+) energy level structure and can operate between 180 and 323 K with a relative sensitivity ranging from 0.7 to 1.7% K(-1). The thermometric parameter is defined as the ratio between the emission intensities of the (5)D0 → (7)F4 transition when the (5)D0 emitting level is excited through the (7)F2 (physiological range) or (7)F1 (down to 180 K) level. Nano and microcrystals of Y2O3:Eu(3+) were chosen as a proof of concept of the operational principles in which both excitation and detection are within the first biological transparent window. A novel and of paramount importance aspect is that the calibration factor can be calculated from the Eu(3+) emission spectrum avoiding the need for new calibration procedures whenever the thermometer operates in different media." @default.
• W2265933462 created "2016-06-24" @default.
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• W2265933462 date "2016-01-01" @default.
• W2265933462 modified "2023-10-06" @default.
• W2265933462 title "Highly-sensitive Eu³⁺ ratiometric thermometers based on excited state absorption with predictable calibration" @default.
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• W2265933462 doi "https://doi.org/10.1039/c6nr00158k" @default.
• W2265933462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26883124" @default.
• W2265933462 hasPublicationYear "2016" @default.
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