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• W2266365741 startingPage "1158" @default.
• W2266365741 abstract "Controlled photoluminescence tuning is important for the optimization and modification of phosphor materials. Herein we report an isostructural solid solution of (CaMg)x(NaSc)1-xSi2O6 (0 < x < 1) in which cation nanosegregation leads to the presence of two dilute Eu(2+) centers. The distinct nanodomains of isostructural (CaMg)Si2O6 and (NaSc)Si2O6 contain a proportional number of Eu(2+) ions with unique, independent spectroscopic signatures. Density functional theory calculations provided a theoretical understanding of the nanosegregation and indicated that the homogeneous solid solution is energetically unstable. It is shown that nanosegregation allows predictive control of color rendering and therefore provides a new method of phosphor development." @default.
• W2266365741 created "2016-06-24" @default.
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• W2266365741 date "2016-01-22" @default.
• W2266365741 modified "2023-10-15" @default.
• W2266365741 title "Tuning of Photoluminescence by Cation Nanosegregation in the (CaMg)_<i>x</i>(NaSc)_1–<i>x</i>Si₂O₆ Solid Solution" @default.
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• W2266365741 doi "https://doi.org/10.1021/jacs.5b12788" @default.
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