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- W2266728073 abstract "Development of chemical compressors for H/sub 2/ processing based on the use of reversible metal hydrides, was stimulated by the discovery of novel alloy hydrides, especially LaNi/sub 5/-based alloys. These latter alloys are easily activated, have good capacity (H/M approx. = 1), provide a useful range of equilibrium H/sub 2/ plateau, and are resistant to O/sub 2/ and H/sub 2/O poisoning. However, they tend to disproportionate toward more stable (and thus less reversible) hydrides when subjected to repeated H/sub 2/ absorption/desorption cycles. We have developed a closed loop H/sub 2/ cycling apparatus, supervised and monitored by an IBM PC. This paper describes the system and discusses results obtained for LaNi/sub 5/, LaNi/sub 4.7/Al/sub 0.3/, and LaNi/sub 4.5/Al/sub 0.5/. The results include change of H/M capacity with cycling and postmortem x-ray analyses." @default.
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- W2266728073 date "1986-01-01" @default.
- W2266728073 modified "2023-09-22" @default.
- W2266728073 title "Disproportionation of A1-modified LaNi/sub 5/ alloys by repeated H/sub 2/ absorption and desorption" @default.
- W2266728073 hasPublicationYear "1986" @default.
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