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• W2267754901 abstract "Resonant two-photon ionization spectroscopy has been used to provide the first rotationally resolved work involving multiply-bonded mixed early–late transition metal dimers. The mixed metal dimers TiCo and ZrCo are shown to possess 2 Σ + ground states, in agreement with a previous matrix isolation ESR (electron spin resonance) study on TiCo. Two previously observed vibronic bands in ZrCo are rotationally resolved, as is one of several newly discovered vibronic transitions in TiCo. Ground-state rotational constants for 48 Ti 59 Co and 90 Zr 59 Co are measured to be B'' 0 = 0.186 15(8) cm –1 and B'' 0 = 0.119 78(5) cm –1 , giving r'' 0 = 1.8508(4) and r'' 0 = 1.9883(4) Å, respectively. In both molecules the ground state conforms to the Hund's case (b β S ) coupling scheme, with Fermi contact interactions between the unpaired σ electron and the 59 Co (I = 7/2) nucleus of b'' F = 0.0468(7) cm –1 for 48 Ti 59 Co and b'' F = 0.0549(6) cm –1 for 90 Zr 59 Co. These values indicate that the unpaired electron occupies a σ orbital having 32% and 37% Co 4s character in TiCo and ZrCo, respectively. All three of the rotationally resolved bands are 2 Π 3/2 ¬ X 2 Σ + transitions. For 90 Zr 59 Co the 0 ¬ 0 and 1 ¬ 0 bands were resolved at ν 0 = 10 496.1452(28) and 10 884.3794(25) cm –1 , giving B' 0 = 0.119 82(6) and B' 1 = 0.121 44(5) cm –1 . For 48 Ti 59 Co the rotationally resolved band has ν 0 = 9873.8342(19) cm –1 and B' = 0.191 07(6) cm –1 . These results are discussed in the context of prior work on these and related molecules. PACS No.: 33.20Eq" @default.
• W2267754901 created "2016-06-24" @default.
• W2267754901 creator A5019942579 @default.
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• W2267754901 date "2001-02-01" @default.
• W2267754901 modified "2023-09-24" @default.
• W2267754901 title "The near infrared 2Π3/2(aβJ) ¬ X 2Σ+(bβS) band systems of TiCo and ZrCo" @default.
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• W2267754901 cites W1997913912 @default.
• W2267754901 cites W2000974863 @default.
• W2267754901 cites W2001657455 @default.
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• W2267754901 cites W2002325847 @default.
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• W2267754901 cites W2034837588 @default.
• W2267754901 cites W2035112973 @default.
• W2267754901 cites W2035532542 @default.
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• W2267754901 cites W2037066099 @default.
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• W2267754901 cites W2069693871 @default.
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• W2267754901 cites W2080075425 @default.
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• W2267754901 doi "https://doi.org/10.1139/p01-014" @default.
• W2267754901 hasPublicationYear "2001" @default.
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