FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2268566230> ?p ?o ?g. }

• W2268566230 endingPage "1239" @default.
• W2268566230 startingPage "1234" @default.
• W2268566230 abstract "Crystallinity and porosity are of central importance for many properties of covalent organic frameworks (COFs), including adsorption, diffusion, and electronic transport. We have developed a new method for strongly enhancing both aspects through the introduction of a modulating agent in the synthesis. This modulator competes with one of the building blocks during the solvothermal COF growth, resulting in highly crystalline frameworks with greatly increased domain sizes reaching several hundreds of nanometers. The obtained materials feature fully accessible pores with an internal surface area of over 2000 m(2) g(-1). Compositional analysis via NMR spectroscopy revealed that the COF-5 structure can form over a wide range of boronic acid-to-catechol ratios, thus producing frameworks with compositions ranging from highly boronic acid-deficient to networks with catechol voids. Visualization of an -SH-functionalized modulating agent via iridium staining revealed that the COF domains are terminated by the modulator. Using functionalized modulators, this synthetic approach thus also provides a new and facile method for the external surface functionalization of COF domains, providing accessible sites for post-synthetic modification reactions. We demonstrate the feasibility of this concept by covalently attaching fluorescent dyes and hydrophilic polymers to the COF surface. We anticipate that the realization of highly crystalline COFs with the option of additional surface functionality will render the modulation concept beneficial for a range of applications, including gas separations, catalysis, and optoelectronics." @default.
• W2268566230 created "2016-06-24" @default.
• W2268566230 creator A5008542262 @default.
• W2268566230 creator A5015165857 @default.
• W2268566230 creator A5017380825 @default.
• W2268566230 creator A5031266184 @default.
• W2268566230 creator A5033447664 @default.
• W2268566230 creator A5043668057 @default.
• W2268566230 creator A5052867387 @default.
• W2268566230 creator A5074580547 @default.
• W2268566230 creator A5075767664 @default.
• W2268566230 date "2016-01-23" @default.
• W2268566230 modified "2023-10-10" @default.
• W2268566230 title "From Highly Crystalline to Outer Surface-Functionalized Covalent Organic Frameworks—A Modulation Approach" @default.
• W2268566230 cites W1965344362 @default.
• W2268566230 cites W1970745606 @default.
• W2268566230 cites W1974323878 @default.
• W2268566230 cites W1980704616 @default.
• W2268566230 cites W1987581091 @default.
• W2268566230 cites W2001202386 @default.
• W2268566230 cites W2001708561 @default.
• W2268566230 cites W2004983112 @default.
• W2268566230 cites W2011852015 @default.
• W2268566230 cites W2013200143 @default.
• W2268566230 cites W2022781082 @default.
• W2268566230 cites W2025286111 @default.
• W2268566230 cites W2027834131 @default.
• W2268566230 cites W2028478923 @default.
• W2268566230 cites W2028495828 @default.
• W2268566230 cites W2034641483 @default.
• W2268566230 cites W2035500973 @default.
• W2268566230 cites W2044944060 @default.
• W2268566230 cites W2045044994 @default.
• W2268566230 cites W2045121472 @default.
• W2268566230 cites W2049145344 @default.
• W2268566230 cites W2049541689 @default.
• W2268566230 cites W2052886839 @default.
• W2268566230 cites W2054034970 @default.
• W2268566230 cites W2056617508 @default.
• W2268566230 cites W2063269279 @default.
• W2268566230 cites W2066470151 @default.
• W2268566230 cites W2073402336 @default.
• W2268566230 cites W2074328510 @default.
• W2268566230 cites W2076489456 @default.
• W2268566230 cites W2079168516 @default.
• W2268566230 cites W2085099674 @default.
• W2268566230 cites W2087346669 @default.
• W2268566230 cites W2087939154 @default.
• W2268566230 cites W2105157003 @default.
• W2268566230 cites W2116053539 @default.
• W2268566230 cites W2118675022 @default.
• W2268566230 cites W2130351060 @default.
• W2268566230 cites W2142268163 @default.
• W2268566230 cites W2169899684 @default.
• W2268566230 cites W2317898558 @default.
• W2268566230 cites W2323852127 @default.
• W2268566230 cites W2329767235 @default.
• W2268566230 cites W2329956991 @default.
• W2268566230 cites W2409778596 @default.
• W2268566230 doi "https://doi.org/10.1021/jacs.5b10708" @default.
• W2268566230 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4742964" @default.
• W2268566230 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26694214" @default.
• W2268566230 hasPublicationYear "2016" @default.
• W2268566230 type Work @default.
• W2268566230 sameAs 2268566230 @default.
• W2268566230 citedByCount "136" @default.
• W2268566230 countsByYear W22685662302016 @default.
• W2268566230 countsByYear W22685662302017 @default.
• W2268566230 countsByYear W22685662302018 @default.
• W2268566230 countsByYear W22685662302019 @default.
• W2268566230 countsByYear W22685662302020 @default.
• W2268566230 countsByYear W22685662302021 @default.
• W2268566230 countsByYear W22685662302022 @default.
• W2268566230 countsByYear W22685662302023 @default.
• W2268566230 crossrefType "journal-article" @default.
• W2268566230 hasAuthorship W2268566230A5008542262 @default.
• W2268566230 hasAuthorship W2268566230A5015165857 @default.
• W2268566230 hasAuthorship W2268566230A5017380825 @default.
• W2268566230 hasAuthorship W2268566230A5031266184 @default.
• W2268566230 hasAuthorship W2268566230A5033447664 @default.
• W2268566230 hasAuthorship W2268566230A5043668057 @default.
• W2268566230 hasAuthorship W2268566230A5052867387 @default.
• W2268566230 hasAuthorship W2268566230A5074580547 @default.
• W2268566230 hasAuthorship W2268566230A5075767664 @default.
• W2268566230 hasBestOaLocation W22685662301 @default.
• W2268566230 hasConcept C107038049 @default.
• W2268566230 hasConcept C115537861 @default.
• W2268566230 hasConcept C123079801 @default.
• W2268566230 hasConcept C127413603 @default.
• W2268566230 hasConcept C138885662 @default.
• W2268566230 hasConcept C147789679 @default.
• W2268566230 hasConcept C150394285 @default.
• W2268566230 hasConcept C171250308 @default.
• W2268566230 hasConcept C178790620 @default.
• W2268566230 hasConcept C179366358 @default.
• W2268566230 hasConcept C180577832 @default.
• W2268566230 hasConcept C185592680 @default.
• W2268566230 hasConcept C192562407 @default.

• next