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- W2269488511 abstract "In this work, we employ dibromocarbene (DBC) radicals to covalently functionalize solution exfoliated graphene via the formation of dibromocyclopropyl adducts. This is achieved using a basic aqueous/organic biphasic reaction mixture to decompose the DBC precursor, bromoform, in conjunction with a phase-transfer catalyst to facilitate ylide formation and carbene migration to graphene substrates. DBC-functionalized graphene (DBC-graphene) was characterized using a range of spectroscopic and analytical techniques to confirm the covalent nature of functionalization. Modified optical and electronic properties of DBC-graphene were investigated using UV–vis spectroscopy, analysis of electrical I–V transport properties, and noncontact terahertz time-domain spectroscopy. The implications of carbene functionalization of graphene are considered in the context of scalable radical functionalization methodologies for bulk-scale graphene processing and controlled band-gap manipulation of graphene." @default.
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- W2269488511 date "2016-02-09" @default.
- W2269488511 modified "2023-10-10" @default.
- W2269488511 title "Covalent Carbene Functionalization of Graphene: Toward Chemical Band-Gap Manipulation" @default.
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- W2269488511 doi "https://doi.org/10.1021/acsami.5b10525" @default.
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