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- W2269984920 abstract "Epicedrol synthase catalyzes the cyclization of achiral diphosphate substrate, (E,E)-farnesyldiphosphate (FPP) into epicedrol. GC–MS analysis of assay extracts obtained by incubating FPP with epicedrol synthase in 21.6 at % H218O buffer showed the molecular ion of 224 for epicedrol. The labeled oxygen study presented here unambiguously demonstrates that the hydroxyl group of the epicedrol synthase enzymatic product, epicedrol, is derived from a water molecule, not from the phosphate moiety of the FPP." @default.
- W2269984920 created "2016-06-24" @default.
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- W2269984920 date "2016-03-01" @default.
- W2269984920 modified "2023-09-24" @default.
- W2269984920 title "Stereoselective quenching of cedryl carbocation in epicedrol biosynthesis" @default.
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- W2269984920 doi "https://doi.org/10.1016/j.tetlet.2016.01.109" @default.
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