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- W2270408814 abstract "Replacement of a dimethyl amino group of the amidobis(amine) nickel(II) pincer complex (1), [(MeN2N)Ni–Cl], by a pyrrolidino group resulted in a new nickel(II) pincer complex (2), [(PyrNMeNN)Ni–Cl]. Complex 2 is an efficient catalyst for Kumada and Suzuki–Miyaura cross-coupling of nonactivated secondary alkyl halides, while complex 1 is largely inactive. The significant activity difference is tentatively attributed to a minimal structural difference, which leads to a more hemilabile ligand." @default.
- W2270408814 created "2016-06-24" @default.
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- W2270408814 date "2015-12-10" @default.
- W2270408814 modified "2023-10-07" @default.
- W2270408814 title "From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides" @default.
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- W2270408814 doi "https://doi.org/10.1021/acscatal.5b02324" @default.
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