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• W2271131689 abstract "Branched allylic amines were prepared by Ir-catalyzed enantioselective allylic aminations with the bulky N-nucleophiles HN(Boc)2 and HNBn2. The products were transformed into N-protected amino aldehydes, which were either reduced or coupled diastereoselectively with organometallic compounds to give vicinal amino alcohols. A formal synthesis of the neurokinin receptor antagonist (+)-L-733060 was carried out as an application." @default.
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• W2271131689 date "2015-12-10" @default.
• W2271131689 modified "2023-09-25" @default.
• W2271131689 title "Iridium-Catalyzed Asymmetric Allyl­ic Substitutions with Bulky ­Amines/Oxidative Double Bond Cleavage - Entry into the Reetz Synthesis of Amino Alcohols" @default.
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• W2271131689 doi "https://doi.org/10.1002/ejoc.201501333" @default.
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