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- W2271604719 abstract "在这份报纸,一系列新光学地活跃的 MeO-BIPHEP-type ligands,(S)-6,6-dimethoxy-2,2-bis(di- p-alkoxyphenyl-phosphine )-1,1-biphenyl [(S)-5b(S)-5e] 被准备并且描绘。从商业地可得到的 triethyl 磷钙土和 m-bromoanisole 开始,光学地活跃的(S)-6,6-dimethoxybiphenyl- 2,2-diyl-bis (磷的酸 diester )被一个改进方法准备并且变换成相应二氯化物,它被用作关键中介与 p-alkoxybenzenemagnesium 溴化物或 p-alkoxyphenyl 锂反应直接给 enantiomerically 纯的 diphosphines 5 。" @default.
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- W2271604719 date "2006-01-01" @default.
- W2271604719 modified "2023-09-24" @default.
- W2271604719 title "Synthesis of New MeO-BIPHEP-type Chiral Diphosphines by an Improved Way" @default.
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