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- W2271637343 abstract "In the present study, potassium chabazite (named as KCHA1 in this study) was synthesized and characterized. Adsorption equilibria of CH4, N2 and CO2 on KCHA1 were volumetrically measured over a wide range of temperature from 77 K to 293.15 K at a pressure up to 120 kPa. The most strongly adsorbed gas is CO2, followed by CH4 and N2 in sequence. Single-component uptake of these gases at 293.15 K, 273.15 K and 253.15 K at low pressure (up to 1 bar) was conducted using a volumetric rig (ASAP2010) to determine adsorption kinetics. The kinetic data were fitted with Fick's law model and the micropore diffusivity were therefore determined. The adsorption kinetics of CO2 was the fastest followed by N2 and CH4. The adsorption rate of N2 and CH4 are believed to be limited by sieving effect, which reaches its limit at low enough temperature and demonstrates 'pore-blockage'. The adsorption kinetics is highly dependent on temperature. The data obtained from this work can be used for kinetic separation process modeling for upgrading natural gas to pipeline quality." @default.
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- W2271637343 date "2010-01-01" @default.
- W2271637343 modified "2023-09-22" @default.
- W2271637343 title "Kinetic Separation of Carbon Dioxide/Nitrogen/Methane by Potassium Chabazite" @default.
- W2271637343 hasPublicationYear "2010" @default.
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