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- W2272259897 abstract "We describe how the 4,5-diazafluoren-9-yl moiety has been utilized in the construction of multinuclear complexes incorporating a ruthenium(II) allenylidene functionality. The coordination chemistry of diazafluorenyl-terminated allenylidene complexes is limited by the sensitivity (instability) of the allenylidene moiety under a variety of synthetic conditions. In contrast the κ2-N,N′-coordination of the diazafluorenyl propargylic alcohol (alkynol) to a metal center prior to allenylidene formation provides a facile route toward the synthesis of multinuclear allenylidene coordination complexes. Our synthetic attempts and successes are discussed in combination with spectroscopic and electronic characterization of the latter cases." @default.
- W2272259897 created "2016-06-24" @default.
- W2272259897 creator A5021731130 @default.
- W2272259897 creator A5025555857 @default.
- W2272259897 creator A5040771863 @default.
- W2272259897 date "2015-10-07" @default.
- W2272259897 modified "2023-09-26" @default.
- W2272259897 title "Coordinating Tectons 4: Coordination Chemistry of the 4,5-Diazafluoren-9-yl Moiety as a Metallo-Ligand for Allenylidene Complexes" @default.
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- W2272259897 doi "https://doi.org/10.1021/acs.organomet.5b00569" @default.
- W2272259897 hasPublicationYear "2015" @default.
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