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- W2272274264 endingPage "1843" @default.
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- W2272274264 abstract "For the efficient utilization of carbon dioxide as feedstock in chemical synthesis, low-energy-barrier CO2 activation is a valuable tool. We report a metal-free approach to reversible CO2 binding under mild conditions based on simple Lewis base adducts with electron-rich phosphines. Variable-temperature NMR studies and DFT calculations reveal almost thermoneutral CO2 binding with low-energy barriers or stable CO2 adduct formation depending on the phosphines donor ability. The most basic phosphine forms an air-stable CO2 adduct that was used as phosphine transfer agent, providing a convenient access to transition-metal complexes with highly electron-rich phosphine ligands relevant to catalysis." @default.
- W2272274264 created "2016-06-24" @default.
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- W2272274264 date "2016-02-04" @default.
- W2272274264 modified "2023-10-14" @default.
- W2272274264 title "Reversible Carbon Dioxide Binding by Simple Lewis Base Adducts with Electron-Rich Phosphines" @default.
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- W2272274264 doi "https://doi.org/10.1021/jacs.5b13116" @default.
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