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- W2272286061 abstract "Hysteresis generally accompanies first order phase transitions which occur in the solid state and for this reason it is important. Its study has, however, been somewhat neglected. It is almost always present in the formation and decomposition of metal hydrides. The vanishing of hysteresis for such a system is noteworthy and this research is concerned with the disappearance. This paper reports that Pd-Ni alloys are reported to form a continuous series of fcc solid solutions over their entire concentration range. The present research concerns hydrogen absorption by several of these, initially homogeneous, Pd-rich alloys before and after they are subjected to a series of hydride formation and decomposition (cycling) phase transitions without intermediate annealing treatments. Pd-Ni alloys are unusual with regard to their hydrogen solubility behavior because the plateau pressures for hybrid formation/decomposition are greater than for pure Pd and the extents of these plateau regions do not markedly decrease with increase of % substituted metal, i.e. Ni. (The latter aspect of their behavior is more unusual than for former.) The increase in plateau pressure seems to be a characteristic of Pd substitutional alloys which have contracted volumes as compared to Pd itself." @default.
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- W2272286061 date "1991-09-01" @default.
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- W2272286061 title "The disappearance of hysteresis for the hydride phase transition in palladium-nickel alloys" @default.
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- W2272286061 doi "https://doi.org/10.1016/0956-716x(91)90295-c" @default.
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