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- W2272597530 abstract "The trapping and mobility of hydrogen in nanostructured tungsten grain boundaries (GBs) have been studied by combining experimental and density functional theory (DFT) data. Experimental results show that nanostructured W coatings with a columnar grain structure and a large number of (1 1 0)/(2 1 1) interfaces retain more H than coarsed grained W samples. To investigate the possible influence of GBs on H retention, a complete energetic analysis of a non-coherent W(1 1 0)/W(1 1 2) interface has been performed employing DFT. Our results show that this kind of non-coherent interface largely attracts point defects (both a H atom and a metallic monovacancy separately) and that the presence of these interfaces contributes to a decrease in the migration energy of the H atoms with respect to the bulk value. When both the W monovacancy and H atom are introduced together into the system, the HV complex becomes the most stable configuration and one of the mechanisms explaining the H retention in the radiation damaged GB observed experimentally." @default.
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- W2272597530 date "2015-09-01" @default.
- W2272597530 modified "2023-10-09" @default.
- W2272597530 title "H trapping and mobility in nanostructured tungsten grain boundaries: a combined experimental and theoretical approach" @default.
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- W2272597530 doi "https://doi.org/10.1088/0029-5515/55/11/113009" @default.
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