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- W2272783503 abstract "Electromotive force (EMF) measurements of oxygen fugacities as a function of stoichiometry have been made on the GdBa{sub 2}Cu{sub 3}O{sub x} system in the temperature range {approximately}400-600 C by means of an oxygen titration technique with an yttria-stabilized zirconia electrolyte. Equations for the variation of oxygen partial pressure with composition and temperature have been derived from our EMF measurements. The shape of the 400 C isotherms as a function of oxygen stoichiometry for the Gd and Nd cuprate systems suggests the presence of miscibility gaps at values of x that are higher than those in the YBa{sub 2}Cu{sub 3}O{sub x} system. For a given oxygen stoichiometry, oxygen partial pressures above Gd-123 and Nd-123 cuprate systems are higher (above x = 6.5) than that for the Y-123 system. A thermodynamic assessment and intercomparison of our partial pressure measurements with the results of related measurements will be presented." @default.
- W2272783503 created "2016-06-24" @default.
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- W2272783503 date "1998-09-29" @default.
- W2272783503 modified "2023-09-23" @default.
- W2272783503 title "Thermodynamic and nonstoichiometric behavior of the GdBa{sub 2}Cu{sub 3}O{sub x} system." @default.
- W2272783503 hasPublicationYear "1998" @default.
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