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• W2273597411 startingPage "4340" @default.
• W2273597411 abstract "Alcohols, the simplest amphiprotic organic compounds, can exhibit either acidic or basic behavior by donating or accepting a proton. In this study, proton dissociation of a model photoacid in solution is explored by using time-resolved spectroscopy, revealing quantitatively for the first time that alcohol acts as a Brønsted base because of H-bonded cluster formation to enhance the reactivity. The protonated alcohol cluster, the alkyl oxonium ion, can be regarded as a key reaction intermediate in the well-established alcohol dehydration reaction. This finding signifies, as in water, the cooperativity of protic solvent molecules to facilitate nonaqueous acid-base reactions." @default.
• W2273597411 created "2016-06-24" @default.
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• W2273597411 date "2016-01-28" @default.
• W2273597411 modified "2023-10-17" @default.
• W2273597411 title "Alcohol Dimer is Requisite to Form an Alkyl Oxonium Ion in the Proton Transfer of a Strong (Photo)Acid to Alcohol" @default.
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• W2273597411 doi "https://doi.org/10.1002/chem.201503948" @default.
• W2273597411 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26757097" @default.
• W2273597411 hasPublicationYear "2016" @default.
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