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- W2273752000 abstract "We have been studying lanthanide complexes derived from various modified calix[4]pyrroles in a range of processes. Initial studies on the trans-N,N'-dimethyl substituted system (1), Figure 1, indicated that the macrocycle greatly hinders two-coordination site chemistry of ancillary ligands for smaller lanthanide ions. The solvent free, monomeric structure of the methyl complex (2), and its low reactivity is a good example of this. We have continued to exploit this outcome, studying species with bulky ancillary ligands, such as (traditionally) chelating diazabutadienes, and -bound ligands, such as cyclopentadienyls and COT. Many outcomes since these initial published examples do not mirror the structures and/or reactivities of [(C5Me5)2SmR] analogues, including solvent mediated Sm(III)/Sm(II) reversibility and ligand based reductions. Importantly, this rare reactivity has been shown to be switchable, dependant on the bulk of the ancillary ligand." @default.
- W2273752000 created "2016-06-24" @default.
- W2273752000 creator A5022245441 @default.
- W2273752000 date "2008-01-01" @default.
- W2273752000 modified "2023-09-26" @default.
- W2273752000 title "Steric Effects in Solvent Mediated Reversible Sm(III)/Sm(II) Processes and Ligand-Based Reduction Chemistry" @default.
- W2273752000 hasPublicationYear "2008" @default.
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