Matches in SemOpenAlex for { <https://semopenalex.org/work/W2273803012> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2273803012 abstract "This is my thesis research on the preparation of borylazadipyrromethene (azaBODIPY) dyes bearing an anchoring group, such as a carboxylic acid group, at the β-pyrrolic position of the azadipyrromethene scaffold. Carboxylate groups form covalent bonds to oxide semiconductors such as TiO2 (n-type) or Cu2O (p-type) in dye-sensitized solar cells (DSCs) or photogalvanic dye-sensitized solar cells (P-DSCs). Oxide-binding azaBODIPY dyes can be used to investigate the rate and mechanism of electron injection from the dyes to the semiconductors. Two different types of azaBODIPY (difluoroboryl and dialkynylboryl) were prepared by following previously developed methods. To convert difluoroborylazaBODIPY to the final dyes having a carboxylic acid in the β-pyrrolic position, several distinct synthetic routes were designed, adopting various reactions, such as halogenation, Sonogashira coupling, Knoevenagel condensation, Grignard reagents, Vilsmeir-Haack, and Steglich esterification. Some of these reactions were successful, but the overall synthesis to the targeted final molecule couldn’t be accomplished. Even though further studies on the synthesis of oxide-binding azaBODIPYs are needed, at least my thesis research suggests what reactions can be implemented to complete this synthesis in the future. Proton NMR (nuclear magnetic resonance) and carbon NMR were commonly used to confirm the synthesized compounds, and sometimes crystallographic information was obtained by XRD (X-ray diffraction) whenever crystals of sufficient size and quality were grown. NMR spectra, interpreted by SpinWorks 3 software, and crystal structures will be introduced in each chapter." @default.
- W2273803012 created "2016-06-24" @default.
- W2273803012 creator A5047958251 @default.
- W2273803012 date "2014-08-01" @default.
- W2273803012 modified "2023-09-26" @default.
- W2273803012 title "Synthesis of Tethering Group on Borylazadipyrromethene Dyes to Apply to Photogalvanic Dye-sensitized Solar Cells" @default.
- W2273803012 hasPublicationYear "2014" @default.
- W2273803012 type Work @default.
- W2273803012 sameAs 2273803012 @default.
- W2273803012 citedByCount "0" @default.
- W2273803012 crossrefType "dissertation" @default.
- W2273803012 hasAuthorship W2273803012A5047958251 @default.
- W2273803012 hasConcept C147789679 @default.
- W2273803012 hasConcept C161790260 @default.
- W2273803012 hasConcept C168395250 @default.
- W2273803012 hasConcept C17525397 @default.
- W2273803012 hasConcept C178790620 @default.
- W2273803012 hasConcept C185592680 @default.
- W2273803012 hasConcept C40875361 @default.
- W2273803012 hasConcept C48421929 @default.
- W2273803012 hasConcept C502130503 @default.
- W2273803012 hasConcept C61442700 @default.
- W2273803012 hasConcept C65973085 @default.
- W2273803012 hasConcept C68801617 @default.
- W2273803012 hasConcept C75473681 @default.
- W2273803012 hasConceptScore W2273803012C147789679 @default.
- W2273803012 hasConceptScore W2273803012C161790260 @default.
- W2273803012 hasConceptScore W2273803012C168395250 @default.
- W2273803012 hasConceptScore W2273803012C17525397 @default.
- W2273803012 hasConceptScore W2273803012C178790620 @default.
- W2273803012 hasConceptScore W2273803012C185592680 @default.
- W2273803012 hasConceptScore W2273803012C40875361 @default.
- W2273803012 hasConceptScore W2273803012C48421929 @default.
- W2273803012 hasConceptScore W2273803012C502130503 @default.
- W2273803012 hasConceptScore W2273803012C61442700 @default.
- W2273803012 hasConceptScore W2273803012C65973085 @default.
- W2273803012 hasConceptScore W2273803012C68801617 @default.
- W2273803012 hasConceptScore W2273803012C75473681 @default.
- W2273803012 hasLocation W22738030121 @default.
- W2273803012 hasOpenAccess W2273803012 @default.
- W2273803012 hasPrimaryLocation W22738030121 @default.
- W2273803012 hasRelatedWork W1965207928 @default.
- W2273803012 hasRelatedWork W1977804984 @default.
- W2273803012 hasRelatedWork W2025422810 @default.
- W2273803012 hasRelatedWork W2029697137 @default.
- W2273803012 hasRelatedWork W2060910742 @default.
- W2273803012 hasRelatedWork W2064690326 @default.
- W2273803012 hasRelatedWork W2093044327 @default.
- W2273803012 hasRelatedWork W2257120257 @default.
- W2273803012 hasRelatedWork W2334496531 @default.
- W2273803012 hasRelatedWork W2767983357 @default.
- W2273803012 hasRelatedWork W2768111872 @default.
- W2273803012 hasRelatedWork W2801538778 @default.
- W2273803012 hasRelatedWork W2901502088 @default.
- W2273803012 hasRelatedWork W2916736165 @default.
- W2273803012 hasRelatedWork W2971702537 @default.
- W2273803012 hasRelatedWork W3021064348 @default.
- W2273803012 hasRelatedWork W3046936206 @default.
- W2273803012 hasRelatedWork W3083546547 @default.
- W2273803012 hasRelatedWork W3143789119 @default.
- W2273803012 hasRelatedWork W3115392677 @default.
- W2273803012 isParatext "false" @default.
- W2273803012 isRetracted "false" @default.
- W2273803012 magId "2273803012" @default.
- W2273803012 workType "dissertation" @default.