Matches in SemOpenAlex for { <https://semopenalex.org/work/W2273851282> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2273851282 endingPage "330" @default.
- W2273851282 startingPage "319" @default.
- W2273851282 abstract "Anion-radical salts (ARS) of 7,7,8,8-tetracyanoquinodimethane (TCNQ) and methyl-TCNQ (MTCNQ) of composition [N-(CnH2n+1)-Pz](TCNQ)m and [N-(CnH2n+1)-Pz](MTCNQ)m, with Pz for pirazinium, n=1, 2,⋯5 and m=1, 2 have been synthesized and investigated. The IR absorption spectra of these compounds have been studied at room temperature. For single crystal and pellet samples of the synthesized salts, electric conductivity has been measured in the temperature range of 77 – 300 K, and the basic electrophysical characteristics were determined. The [N-CH3-Pz](TCNQ) compound was revealed to be an organic metal undergoing a metal-dielectric transition when cooled below 120 K, the lowest temperature which has ever been achieved for ARS of TCNQ with close-type cations. The conductivity of [N-(CnH2n+1)-Pz](MTCNQ)m salts has been found to be substantial and comparable with that of analogous TCNQ-based compounds. In this, the above compounds are noticeably distinguished from the ARS with cations based on other nitrogen-containing heterocycles. In crystals of the [N-C2H5-Pz](MTCNQ)2 salt, the existence of a highly quasi-two-dimensional conducting state is expected, despite this being atypical for TCNQ-based ARS." @default.
- W2273851282 created "2016-06-24" @default.
- W2273851282 creator A5025271898 @default.
- W2273851282 creator A5056308251 @default.
- W2273851282 creator A5060530648 @default.
- W2273851282 creator A5071357170 @default.
- W2273851282 creator A5089577410 @default.
- W2273851282 creator A5091705801 @default.
- W2273851282 date "2006-01-12" @default.
- W2273851282 modified "2023-09-23" @default.
- W2273851282 title "Spectral and Electrophysical Properties of Anion-Radical Salts of TCNQ and Methyl-TCNQ with N-Alkylpirazinium Cations" @default.
- W2273851282 cites W1971813006 @default.
- W2273851282 cites W1975646186 @default.
- W2273851282 cites W1988304487 @default.
- W2273851282 cites W2001920115 @default.
- W2273851282 cites W2004594958 @default.
- W2273851282 cites W2060133815 @default.
- W2273851282 cites W2062682639 @default.
- W2273851282 cites W2085777176 @default.
- W2273851282 cites W2089430481 @default.
- W2273851282 cites W2091974983 @default.
- W2273851282 cites W2166280640 @default.
- W2273851282 doi "https://doi.org/10.1007/1-4020-2396-0_28" @default.
- W2273851282 hasPublicationYear "2006" @default.
- W2273851282 type Work @default.
- W2273851282 sameAs 2273851282 @default.
- W2273851282 citedByCount "1" @default.
- W2273851282 crossrefType "book-chapter" @default.
- W2273851282 hasAuthorship W2273851282A5025271898 @default.
- W2273851282 hasAuthorship W2273851282A5056308251 @default.
- W2273851282 hasAuthorship W2273851282A5060530648 @default.
- W2273851282 hasAuthorship W2273851282A5071357170 @default.
- W2273851282 hasAuthorship W2273851282A5089577410 @default.
- W2273851282 hasAuthorship W2273851282A5091705801 @default.
- W2273851282 hasConcept C131540310 @default.
- W2273851282 hasConcept C145148216 @default.
- W2273851282 hasConcept C147789679 @default.
- W2273851282 hasConcept C178790620 @default.
- W2273851282 hasConcept C179104552 @default.
- W2273851282 hasConcept C185592680 @default.
- W2273851282 hasConcept C2776371256 @default.
- W2273851282 hasConcept C2780713452 @default.
- W2273851282 hasConcept C32909587 @default.
- W2273851282 hasConcept C544153396 @default.
- W2273851282 hasConcept C73922627 @default.
- W2273851282 hasConcept C8010536 @default.
- W2273851282 hasConceptScore W2273851282C131540310 @default.
- W2273851282 hasConceptScore W2273851282C145148216 @default.
- W2273851282 hasConceptScore W2273851282C147789679 @default.
- W2273851282 hasConceptScore W2273851282C178790620 @default.
- W2273851282 hasConceptScore W2273851282C179104552 @default.
- W2273851282 hasConceptScore W2273851282C185592680 @default.
- W2273851282 hasConceptScore W2273851282C2776371256 @default.
- W2273851282 hasConceptScore W2273851282C2780713452 @default.
- W2273851282 hasConceptScore W2273851282C32909587 @default.
- W2273851282 hasConceptScore W2273851282C544153396 @default.
- W2273851282 hasConceptScore W2273851282C73922627 @default.
- W2273851282 hasConceptScore W2273851282C8010536 @default.
- W2273851282 hasLocation W22738512821 @default.
- W2273851282 hasOpenAccess W2273851282 @default.
- W2273851282 hasPrimaryLocation W22738512821 @default.
- W2273851282 hasRelatedWork W1966240311 @default.
- W2273851282 hasRelatedWork W1970114912 @default.
- W2273851282 hasRelatedWork W1984364037 @default.
- W2273851282 hasRelatedWork W2033313020 @default.
- W2273851282 hasRelatedWork W2067775246 @default.
- W2273851282 hasRelatedWork W2078915857 @default.
- W2273851282 hasRelatedWork W2084051696 @default.
- W2273851282 hasRelatedWork W2168089132 @default.
- W2273851282 hasRelatedWork W2895473214 @default.
- W2273851282 hasRelatedWork W4308363008 @default.
- W2273851282 isParatext "false" @default.
- W2273851282 isRetracted "false" @default.
- W2273851282 magId "2273851282" @default.
- W2273851282 workType "book-chapter" @default.