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- W2274292023 endingPage "3985" @default.
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- W2274292023 abstract "Abstract Any synthetic transformation using contact‐explosives primary amines and hypervalent iodine(III) (phenyliodine diacetate) in constrained media (extreme conditions) is practically impossible. Herein, we report a method of controlling the explosion into a successful chemical reaction using the acid‐salt NaHSO 4 . As a proof‐of‐concept, we considered mechanochemical (ball‐milling) cross dehydrogenative coupling (CDC) reaction for the amidation of aldehydes via CH activation. An isothermal titration calorimetric (ITC) study was helpful to understand the enthalpy changes during the reactions before and after addition of NaHSO 4 . magnified image" @default.
- W2274292023 created "2016-06-24" @default.
- W2274292023 creator A5025741012 @default.
- W2274292023 creator A5026932849 @default.
- W2274292023 date "2015-12-09" @default.
- W2274292023 modified "2023-10-18" @default.
- W2274292023 title "Transformation of Contact-Explosives Primary Amines and Iodine(III) into a Successful Chemical Reaction under Solvent-Free Ball Milling Conditions" @default.
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- W2274292023 doi "https://doi.org/10.1002/adsc.201500914" @default.
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