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- W2274510836 abstract "Abstract In a study of the protection of vulcanized rubber against aging by combinations of the zinc salt of mercaptobenzimidazole and “true” antioxygenic agents, it has been found that such combinations have a synergetic effect of considerable magnitude in the protection of vulcanizates which are accelerated by mercaptobenzothiazole. On the other hand, in the case of vulcanizates accelerated by diphenylguanidine, the effect is slight or even negligible. On the assumption, therefore, that the nature of the accelerator has a great influence on the effectiveness of the protective agents, the latter were classified with respect to the accelerators used. In this way it was established that bis-(2-hydroxy-3-tert-butyl-5-methylphenyl) methane, when employed alone is by far the best protective agent against the aging of vulcanized rubber accelerated by diphenylguanidine. In addition by combining this “true” antioxygenic agent with the zinc salt of mercaptobenzimidazole it was found that only slightly greater protection can be attained than is possible by the antioxygenic agent alone. Consequently in this case one should not speak of a synergetic effect. The experiments lead quite definitely to the conclusion that the mechanism of protection against aging when a deactivating agent is present depends upon whether the accelerator employed is mercaptobenzothiazole or diphenylguanidine." @default.
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- W2274510836 date "1954-03-01" @default.
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- W2274510836 title "Acceleration and Aging" @default.
- W2274510836 doi "https://doi.org/10.5254/1.3543464" @default.
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