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• W2274639714 abstract "Catalyst support materials of tetragonal ZrO2, stabilized by either La2O3 (La2O3-ZrO2) or CeO2 (CeO2-ZrO2), were synthesized under hydrothermal conditions at 200 °C with NH4OH or tetramethylammonium hydroxide as the mineralizer. From in situ synchrotron powder X-ray diffraction and small-angle X-ray scattering measurements, the calcined La2O3-ZrO2 and CeO2-ZrO2 supports were nonporous nanocrystallites that exhibited rectangular shapes with a thermal stability of up to 1000 °C in air. These supports had an average size of ∼ 10 nm and a surface area of 59-97 m(2)/g. The catalysts Pt/La2O3-ZrO2 and Pt/CeO2-ZrO2 were prepared by using atomic layer deposition with varying Pt loadings from 6.3 to 12.4 wt %. Monodispersed Pt nanoparticles of ∼ 3 nm were obtained for these catalysts. The incorporation of La2O3 and CeO2 into the t-ZrO2 structure did not affect the nature of the active sites for the Pt/ZrO2 catalysts for the water-gas shift reaction." @default.
• W2274639714 created "2016-06-24" @default.
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• W2274639714 date "2016-02-15" @default.
• W2274639714 modified "2023-10-16" @default.
• W2274639714 title "High Thermal Stability of La₂O₃- and CeO₂-Stabilized Tetragonal ZrO₂" @default.
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• W2274639714 doi "https://doi.org/10.1021/acs.inorgchem.5b02810" @default.
• W2274639714 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26878202" @default.
• W2274639714 hasPublicationYear "2016" @default.
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