Matches in SemOpenAlex for { <https://semopenalex.org/work/W2274706907> ?p ?o ?g. }
- W2274706907 endingPage "27297" @default.
- W2274706907 startingPage "27291" @default.
- W2274706907 abstract "Radical polymerization in nanoscale channels of porous coordination polymers has been explored as a promising technique to control the properties of product polymers. In particular, tacticity of poly(methyl methacrylate) was successfully controlled by utilizing one-dimensional channels of [M2(L)2TED]n type of porous coordination polymers by changing the dicarboxylate ligand L. Toward understanding the atomistic mechanism of this tacticity control, we computationally studied the behavior of methyl methacrylate monomers in the one-dimensional channels by molecular dynamics simulations. Smooth monomer diffusion in the direction along the channel was shown as expected from the channel shape. In addition, we confirmed that the monomers can pass through the narrow apertures between the channels and can diffuse slowly in the direction perpendicular to the channel. In the channels, the ratio of the s-trans and s-cis conformations of the monomers is different from that in monomer liquid. We found two factors affecting these behaviors: the host–guest electrostatic interactions and the anisotropic shape of the channels by the planar and nonplanar dicarboxylate ligands (L). These factors will contribute to understanding of the tacticity modification mechanism by different ligands from the atomistic point of view." @default.
- W2274706907 created "2016-06-24" @default.
- W2274706907 creator A5004653016 @default.
- W2274706907 creator A5052323916 @default.
- W2274706907 creator A5062176232 @default.
- W2274706907 date "2015-12-02" @default.
- W2274706907 modified "2023-10-16" @default.
- W2274706907 title "Control of Diffusion and Conformation Behavior of Methyl Methacrylate Monomer by Phenylene Fin in Porous Coordination Polymers" @default.
- W2274706907 cites W1964462357 @default.
- W2274706907 cites W1964953510 @default.
- W2274706907 cites W1970945774 @default.
- W2274706907 cites W1973376251 @default.
- W2274706907 cites W1973467413 @default.
- W2274706907 cites W1987134427 @default.
- W2274706907 cites W1990888273 @default.
- W2274706907 cites W1992620182 @default.
- W2274706907 cites W1997094547 @default.
- W2274706907 cites W1999937609 @default.
- W2274706907 cites W2002615184 @default.
- W2274706907 cites W2010528943 @default.
- W2274706907 cites W2011334955 @default.
- W2274706907 cites W2018133543 @default.
- W2274706907 cites W2022167379 @default.
- W2274706907 cites W2029667189 @default.
- W2274706907 cites W2033778897 @default.
- W2274706907 cites W2040247619 @default.
- W2274706907 cites W2048708337 @default.
- W2274706907 cites W2055638302 @default.
- W2274706907 cites W2065783009 @default.
- W2274706907 cites W2078399627 @default.
- W2274706907 cites W2088771495 @default.
- W2274706907 cites W2100910816 @default.
- W2274706907 cites W2102457549 @default.
- W2274706907 cites W2103829561 @default.
- W2274706907 cites W2105218596 @default.
- W2274706907 cites W2118233996 @default.
- W2274706907 cites W2123874510 @default.
- W2274706907 cites W2130051656 @default.
- W2274706907 cites W2131939032 @default.
- W2274706907 cites W2133084791 @default.
- W2274706907 cites W2133361771 @default.
- W2274706907 cites W2133399558 @default.
- W2274706907 cites W2138429893 @default.
- W2274706907 cites W2147774255 @default.
- W2274706907 cites W2147993766 @default.
- W2274706907 cites W2158817381 @default.
- W2274706907 cites W2171081520 @default.
- W2274706907 cites W2303854719 @default.
- W2274706907 cites W2313650448 @default.
- W2274706907 cites W2315951222 @default.
- W2274706907 cites W2326066359 @default.
- W2274706907 cites W2326405214 @default.
- W2274706907 cites W2333927335 @default.
- W2274706907 cites W2335472345 @default.
- W2274706907 cites W2515736643 @default.
- W2274706907 cites W4249652017 @default.
- W2274706907 cites W4366807521 @default.
- W2274706907 cites W777173922 @default.
- W2274706907 doi "https://doi.org/10.1021/acs.jpcc.5b09332" @default.
- W2274706907 hasPublicationYear "2015" @default.
- W2274706907 type Work @default.
- W2274706907 sameAs 2274706907 @default.
- W2274706907 citedByCount "10" @default.
- W2274706907 countsByYear W22747069072018 @default.
- W2274706907 countsByYear W22747069072019 @default.
- W2274706907 countsByYear W22747069072020 @default.
- W2274706907 countsByYear W22747069072021 @default.
- W2274706907 countsByYear W22747069072022 @default.
- W2274706907 countsByYear W22747069072023 @default.
- W2274706907 crossrefType "journal-article" @default.
- W2274706907 hasAuthorship W2274706907A5004653016 @default.
- W2274706907 hasAuthorship W2274706907A5052323916 @default.
- W2274706907 hasAuthorship W2274706907A5062176232 @default.
- W2274706907 hasConcept C121332964 @default.
- W2274706907 hasConcept C132050475 @default.
- W2274706907 hasConcept C159467904 @default.
- W2274706907 hasConcept C159985019 @default.
- W2274706907 hasConcept C166940927 @default.
- W2274706907 hasConcept C185592680 @default.
- W2274706907 hasConcept C188027245 @default.
- W2274706907 hasConcept C192562407 @default.
- W2274706907 hasConcept C2777935641 @default.
- W2274706907 hasConcept C44228677 @default.
- W2274706907 hasConcept C521977710 @default.
- W2274706907 hasConcept C58018886 @default.
- W2274706907 hasConcept C69357855 @default.
- W2274706907 hasConcept C97355855 @default.
- W2274706907 hasConceptScore W2274706907C121332964 @default.
- W2274706907 hasConceptScore W2274706907C132050475 @default.
- W2274706907 hasConceptScore W2274706907C159467904 @default.
- W2274706907 hasConceptScore W2274706907C159985019 @default.
- W2274706907 hasConceptScore W2274706907C166940927 @default.
- W2274706907 hasConceptScore W2274706907C185592680 @default.
- W2274706907 hasConceptScore W2274706907C188027245 @default.
- W2274706907 hasConceptScore W2274706907C192562407 @default.
- W2274706907 hasConceptScore W2274706907C2777935641 @default.
- W2274706907 hasConceptScore W2274706907C44228677 @default.
- W2274706907 hasConceptScore W2274706907C521977710 @default.