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- W2275100770 abstract "ABSTRACTA novel ester homologous series of rich mesomorphism and low temperatures with unexpected phase behaviors of eleven homologues was synthesized and studied with a view to understanding and establishing the relation between mesomorphic behaviour and the molecular structure of a series 4-(4′-n-alkoxybenzoyloxy)-4″-chlorobenzyl cinnamates. All the members of the novel series are enantiotropically smectogenic and the octyloxy (C8) to hexadecyloxy (C16) homologues are enantiotropically nematogenic, in addition to smectogenic. Odd–even effect is observed for Sm‒I/Sm‒N transition curve but it is absent for N‒I transition curve. Textures of nematic phase are threaded or Schlieren and that of the smectic phase are fan shaped or batonates of smectic-A type phase or Smectic-C type for C16 homologues as judged directly from a heating stage of an optical polarizing microscopy. Analytical and spectral data confirmed the molecular structures of novel homologues. Mesomorphic properties of present series are compar..." @default.
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- W2275100770 date "2016-01-22" @default.
- W2275100770 modified "2023-09-26" @default.
- W2275100770 title "Mesomorphism dependence on molecular rigidity with reference to ‒CH˭CH‒ unit of central bridge" @default.
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