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• W2275333553 abstract "Two novel rare-earth beryllium borates ReBe2B5O11 (Re = Y, Gd) have been discovered. These materials possess a unique structural feature with a platelike infinite ∞2[Be2B5O11]3– superlayer, which is first found in beryllium borates. The superlayer can be seen as sandwich-shaped with ∞1[B4O8]4– chains linking up with a ∞2[Be2BO5]3– sublayer above and below via the B–O–Be bond. Each ∞2[Be2B5O11]3– layer is further connected to the neighboring layer through Re3+ cations coordinating with O atoms. Both of these two crystals have very short cutoff wavelengths below 200 nm and exhibit relatively large nonlinear-optical (NLO) effects, indicating their promising applications as good deep-UV NLO crystals." @default.
• W2275333553 created "2016-06-24" @default.
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• W2275333553 date "2014-01-28" @default.
• W2275333553 modified "2023-10-16" @default.
• W2275333553 title "ReBe₂B₅O₁₁ (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials" @default.
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• W2275333553 doi "https://doi.org/10.1021/ic4029436" @default.
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