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- W2275431616 endingPage "191" @default.
- W2275431616 startingPage "133" @default.
- W2275431616 abstract "This chapter focuses on nanoscopic metal fluorides and hydroxide fluorides prepared via a recently explored fluorolytic sol–gel synthesis approach. Metal fluoride phases obtained via this route exhibit exciting catalytic properties making them distinctly different as compared with their classically prepared homologues. As a result, very strong solid Lewis acids are available that give access to new catalytic reactions with sometimes unexpectedly high conversion degrees and selectivity. Even more interestingly, metal hydroxide fluorides can be obtained via this synthesis route, being not at all accessible via any other approach. The fluorolytic sol–gel synthesis allows an adjustment of the hydroxide to fluoride ratio over a wide range. Thus, biacidic (Bronsted and Lewis) solids with tunable Lewis to Bronsted acidity are available that show interesting catalytic properties in a variety of different reactions. Finally, these new nanometal fluorides, due to their very high surface areas and distinct acidic properties, are excellent candidates as support for many novel metal-catalyzed reactions, showing surprising synergistic effects. This chapter will briefly outline the synthesis approach of the fluorolytic sol–gel route with some mechanistic aspects, will present characteristic bulk and surface properties, and will give several examples of novel catalytic applications of nanoscaled metal fluorides in purely Lewis acid and in biacidic catalyzed reactions, and will also exemplarily show the potential of these new materials as supports for heterogeneous catalytic reactions." @default.
- W2275431616 created "2016-06-24" @default.
- W2275431616 creator A5036870633 @default.
- W2275431616 creator A5082950377 @default.
- W2275431616 date "2016-01-01" @default.
- W2275431616 modified "2023-09-25" @default.
- W2275431616 title "Nanoscaled Metal Fluorides in Heterogeneous Catalysis" @default.
- W2275431616 cites W1784887409 @default.
- W2275431616 cites W194065223 @default.
- W2275431616 cites W1964265231 @default.
- W2275431616 cites W1965861470 @default.
- W2275431616 cites W1966146468 @default.
- W2275431616 cites W1966892664 @default.
- W2275431616 cites W1970931223 @default.
- W2275431616 cites W1973968886 @default.
- W2275431616 cites W1975925700 @default.
- W2275431616 cites W1975944613 @default.
- W2275431616 cites W1976477353 @default.
- W2275431616 cites W1977159603 @default.
- W2275431616 cites W1977627942 @default.
- W2275431616 cites W1979421054 @default.
- W2275431616 cites W1979597174 @default.
- W2275431616 cites W1981711511 @default.
- W2275431616 cites W1982516235 @default.
- W2275431616 cites W1982859185 @default.
- W2275431616 cites W1984410002 @default.
- W2275431616 cites W1985069924 @default.
- W2275431616 cites W1986173570 @default.
- W2275431616 cites W1987301758 @default.
- W2275431616 cites W1987643155 @default.
- W2275431616 cites W1988277551 @default.
- W2275431616 cites W1989751870 @default.
- W2275431616 cites W1990316433 @default.
- W2275431616 cites W1990610199 @default.
- W2275431616 cites W1990985920 @default.
- W2275431616 cites W1991319748 @default.
- W2275431616 cites W1992373892 @default.
- W2275431616 cites W1993923310 @default.
- W2275431616 cites W1995032415 @default.
- W2275431616 cites W1995368512 @default.
- W2275431616 cites W1998846609 @default.
- W2275431616 cites W2000120698 @default.
- W2275431616 cites W2001538555 @default.
- W2275431616 cites W2002123062 @default.
- W2275431616 cites W2002644266 @default.
- W2275431616 cites W2003476010 @default.
- W2275431616 cites W2004141135 @default.
- W2275431616 cites W2006794739 @default.
- W2275431616 cites W2009805938 @default.
- W2275431616 cites W2011286334 @default.
- W2275431616 cites W2013147035 @default.
- W2275431616 cites W2015160772 @default.
- W2275431616 cites W2015424281 @default.
- W2275431616 cites W2015477872 @default.
- W2275431616 cites W2017226010 @default.
- W2275431616 cites W2018173357 @default.
- W2275431616 cites W2018318099 @default.
- W2275431616 cites W2018366372 @default.
- W2275431616 cites W2018690131 @default.
- W2275431616 cites W2020489040 @default.
- W2275431616 cites W2024061852 @default.
- W2275431616 cites W2025026893 @default.
- W2275431616 cites W2025308280 @default.
- W2275431616 cites W2027262146 @default.
- W2275431616 cites W2029085477 @default.
- W2275431616 cites W2029456847 @default.
- W2275431616 cites W2031872287 @default.
- W2275431616 cites W2032135163 @default.
- W2275431616 cites W2034051559 @default.
- W2275431616 cites W2034914607 @default.
- W2275431616 cites W2036683485 @default.
- W2275431616 cites W2038698974 @default.
- W2275431616 cites W2039322258 @default.
- W2275431616 cites W2040552624 @default.
- W2275431616 cites W2041169847 @default.
- W2275431616 cites W2043972781 @default.
- W2275431616 cites W2045151345 @default.
- W2275431616 cites W2045667282 @default.
- W2275431616 cites W2045879549 @default.
- W2275431616 cites W2048830301 @default.
- W2275431616 cites W2051019906 @default.
- W2275431616 cites W2051399921 @default.
- W2275431616 cites W2051580513 @default.
- W2275431616 cites W2052026247 @default.
- W2275431616 cites W2052836851 @default.
- W2275431616 cites W2053026864 @default.
- W2275431616 cites W2055828623 @default.
- W2275431616 cites W2056195354 @default.
- W2275431616 cites W2056495146 @default.
- W2275431616 cites W2058272462 @default.
- W2275431616 cites W2058990995 @default.
- W2275431616 cites W2061257451 @default.
- W2275431616 cites W2061910845 @default.
- W2275431616 cites W2062903667 @default.
- W2275431616 cites W2065044190 @default.
- W2275431616 cites W2065319282 @default.
- W2275431616 cites W2066038571 @default.
- W2275431616 cites W2072841127 @default.