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• W2275446648 endingPage "145701" @default.
• W2275446648 startingPage "145701" @default.
• W2275446648 abstract "P-nitrophenol (4-NP) and hydrazine hydrate are considered to be highly toxic pollutants in wastewater, and it is of great importance to remove them. Herein, TiO2-loaded Co0.85Se thin films with heterostructure were successfully synthesized by a hydrothermal route. The as-synthesized samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy, transmission electron microscopy and selective-area electron diffraction. The results demonstrate that TiO2 nanoparticles with a size of about 10 nm are easily loaded on the surface of graphene-like Co0.85Se nanofilms, and the NH3 · H2O plays an important role in the generation and crystallization of TiO2 nanoparticles. Brunauer-Emmett-Teller measurement shows that the obtained nanocomposites have a larger specific surface area (199.3 m(2) g(-1)) than that of Co0.85Se nanofilms (55.17 m(2) g(-1)) and TiO2 nanoparticles (19.49 m(2) g(-1)). The catalytic tests indicate Co0.85Se-TiO2 nanofilms have the highest activity for 4-NP reduction and hydrazine hydrate decomposition within 10 min and 8 min, respectively, compared with the corresponding precursor Co0.85Se nanofilms and TiO2 nanoparticles. The enhanced catalytic performance can be attributed to the larger specific surface area and higher rate of interfacial charge transfer in the heterojunction than that of the single components. In addition, recycling tests show that the as-synthesized sample presents stable conversion efficiency for 4-NP reduction." @default.
• W2275446648 created "2016-06-24" @default.
• W2275446648 creator A5015138163 @default.
• W2275446648 creator A5028765513 @default.
• W2275446648 creator A5034532077 @default.
• W2275446648 creator A5063458441 @default.
• W2275446648 creator A5064498707 @default.
• W2275446648 creator A5065144519 @default.
• W2275446648 date "2016-02-23" @default.
• W2275446648 modified "2023-09-26" @default.
• W2275446648 title "Synthesis of TiO₂-loaded Co_0.85Se thin films with heterostructure and their enhanced catalytic activity for p-nitrophenol reduction and hydrazine hydrate decomposition" @default.
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• W2275446648 doi "https://doi.org/10.1088/0957-4484/27/14/145701" @default.
• W2275446648 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26903086" @default.
• W2275446648 hasPublicationYear "2016" @default.
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