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- W2275661350 abstract "Bimetallic rhodium complexes based on the novel binucleating tatraphosphine ligand system racemic-Et{sub 2}PCH{sub 2}CH{sub 2}P(Ph)CH{sub 2}P(Ph)CH{sub 2}CH{sub 2}PEt{sub 2}, et,ph-P4, are highly active and selective hydroformylation catalysts that make use of bimetallic cooperativity to operate. The versatility of the previously reported hydroformylation ligand (et,ph-P4) has been expanded by changing the substituents on the internal phosphorus atoms. This was made possible by the ability to synthesize a variety of substituted methylene bridges of the type (H)RPCH{sub 2}PR(H). These were made by employing a new Grignard-like synthesis with bis(dichlorophosphine)methane (Cl{sub 2}PCH{sub 2}PCl{sub 2}). This new Grignard-like chemistry has also allowed us to synthesize, cleanly and quantitatively, previously unattainable disubstituted alkyl phosphines of the type P(H)R{sub 2} and P(Cl)R{sub 2}." @default.
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- W2275661350 date "1996-10-01" @default.
- W2275661350 modified "2023-09-27" @default.
- W2275661350 title "Novel synthesis of modified tetraphosphine ligands for bimetallic hydroformylation catalysis" @default.
- W2275661350 hasPublicationYear "1996" @default.
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