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- W2276059969 abstract "The asymmetric aldol reaction was carried out by deprotonating an N-propionyl derivative of alcohol-derived terpene cis-myrtanol, chiral auxiliary with lithium diisopropylamide (LDA), and then treating the Z-lithium enolate with benzaldehyde. Unfortunately, analysis of H-1 NMR spectrum of the crude aldol product showed poor diastereoselectivity. The boron enolate methodology was adopted to improve it. The boron enolate was generated by treatment of the N-propionyl derivative with Bu2BOTf and diisopropylethylamine and then treated with benzaldehyde. Analysis of H-1 NMR spectrum of the crude aldol product obtained revealed an excellent diastereoselectivity." @default.
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- W2276059969 date "2003-01-01" @default.
- W2276059969 modified "2023-09-23" @default.
- W2276059969 title "Asymmetric aldol reactions of an N-propionyl derivative of chiral auxiliary derived from terpene alcohol cis-myrtanol with benzaldehyde" @default.
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