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- W2276135930 abstract "The cis-hydrindanol skeleton can be found in the structures of many natural products, such as Botrydial、Sesquiterpene and Presilphiperfolan-8b-ol. Thus, in this thesis we report a short entry to functionalized cis-Hydroindenols from Diels-Alder reactions with masked o-benzoquinone (MOB) and the Ring- Rearrangement Metathesis (RRM).The bicyclo[2.2.2]octenone derivatives prepared for the RRM reaction were obtained from the Diels-Alder reaction of MOBs with various dienophiles, and followed by the addition of allylmagnesium bromide-CeCl3 complex. We have then successfully constructed cis-hydrindanol skeleton by this strategy and explored the scope and limitation of the target synthetic method." @default.
- W2276135930 created "2016-06-24" @default.
- W2276135930 creator A5022971851 @default.
- W2276135930 date "2008-01-01" @default.
- W2276135930 modified "2023-09-25" @default.
- W2276135930 title "2-烯丙基雙環[2.2.2]辛烯化合物的環重排置換反應之研究; 由2-甲氧酚製備順式-八氫茚醇" @default.
- W2276135930 doi "https://doi.org/10.6843/nthu.2008.00357" @default.
- W2276135930 hasPublicationYear "2008" @default.
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