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- W2276189428 abstract "Abstract β-cyclodextrin grafted on lignin ( l -β-CD) was prepared by the reaction of β-cyclodextrin (β-CD) and lignin with epichlorohydrin (EPI) as a cross-linking agent. The polymer was characterized by Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Scanning electron microscopy (SEM), and solid-state nuclear magnetic resonance spectroscopy (CP-MAS-NMR). It was used as an inverse phase transfer catalyst for selective oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) with hydrogen peroxide as the oxidant. The effects of various reaction variables, e.g., catalyst, the amount of catalyst, stirring speed, reaction temperature, oxidant, and cocatalyst on the catalytic performances were investigated. Under optimal conditions, high selectivity (>99%) was observed for the oxidation of BzOH under rather mild conditions. A plausible mechanism for the liquid-solid phase oxidation of BzOH has been proposed. Synergistic effects based on weak interactions between catalyst and support played an important role for the effective oxidation of BzOH under solution condition. The catalyst can be easily recycled and reused without a significant loss in reaction activity and selectivity, which would lead to its potential application foreground for environmental friendly synthesis of BzH." @default.
- W2276189428 created "2016-06-24" @default.
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- W2276189428 date "2016-04-01" @default.
- W2276189428 modified "2023-09-27" @default.
- W2276189428 title "β-cyclodextrin grafted on lignin as inverse phase transfer catalyst for the oxidation of benzyl alcohol in H2O" @default.
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- W2276189428 doi "https://doi.org/10.1016/j.tet.2016.02.036" @default.
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