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- W2276207810 endingPage "7791" @default.
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- W2276207810 abstract "Oligosaccharide synthesis is still a challenging task despite the advent of modern glycosidation techniques. Herein, alkynyl glycosyl carbonates are shown to be stable glycosyl donors that can be activated catalytically by gold and silver salts at 25 °C in just 15 min to produce glycosides in excellent yields. Benzoyl glycosyl carbonate donors are solid compounds with a long shelf life. This operationally simple protocol was found to be highly efficient for the synthesis of nucleosides, amino acids, and phenolic and azido glycoconjugates. Repeated use of the carbonate glycosidation method enabled the highly convergent synthesis of tridecaarabinomannan in a rapid manner." @default.
- W2276207810 created "2016-06-24" @default.
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- W2276207810 date "2016-02-16" @default.
- W2276207810 modified "2023-10-17" @default.
- W2276207810 title "Stable Alkynyl Glycosyl Carbonates: Catalytic Anomeric Activation and Synthesis of a Tridecasaccharide Reminiscent of <i>Mycobacterium tuberculosis</i> Cell Wall Lipoarabinomannan" @default.
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- W2276207810 doi "https://doi.org/10.1002/anie.201511695" @default.
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