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• W2276249767 abstract "Products and rates of the reactions of 1,1,1-Trichlorethane, Isobutylchloride, Di-t-Butyl-Peroxide, t-Butyl-Peroxy-Pivalate and Dimethoxymethane with Fluorine atoms are examined in the gas phase in an isothermal flow reactor with continuous molecular beam sampling and mass spectrometric analysis at pressure of 1-2 mbar. The radicals Methyl, Ethyl, Allyl, 1-Propyl, 2-Propyl, 1-Butyl, 2-Butyl, Isobutyl, t-Butyl, t-Butyl, c-Pentadienyl, c-Pentyl, c-Hexyl, c-Heptyl, c-Heptyl, c-Octyl, Methoxymethyl and 2-Chlor-2-Methyl-Propyl are formed by Hydrogen atom abstraction at their corresponding precursor molecules in the gas phase at pressure of 1 - 2 mbar. They are specifically detected by resonance enhanced multi photon ionization (REMPI) in the wavelength region of 335-540 nm and coupled time of flight mass spectrometer (TOF). In this way for some of the mentioned radicals the usage of partially deuterated compounds is necessary. The 1,1,1-Trichlorethyl radical is generated by H-atom abstraction at 1,1,1-Trichlorethan. It is detected by electron impact ionization (EI) in a sector field mass spectrometer. The kinetics of the reactions of the radicals Methyl, Allyl, 1-Propyl, 2-Propyl, 1-Butyl, 2-Butyl, Isobutyl, t-Butyl, c-Pentadienyl, c-Pentyl, c-Heptyl, c-Octyl, Methoxymethyl, 2-Chlor-2-Methyl-Propyl and 1,1,1-Trichlorethyl with Oxygen atoms at room temperature is determined. The temperature dependence of the reaction of c-Octyl with O-atoms is measured in the interval 278 K - 363 K, that of the reaction of Trichlorethyl with O-atoms in interval 243 K - 363 K. The rates of the reactions Methyl + O and Ethyl + O are examined on an isotopic effect. The products of the reaction t-Butyl + O are investigated in a static photolysis cell by FTIR-detection. The kinetics of the reactions of the radicals t-Butyl, c-Pentadienyl, c-Heptyl, c-Octyl and 2-Chlor-2-Methyl-Propyl with oxygen molecules is determined at room temperature. For the reaction of c-Octyl with molecular oxygen the temperature dependence is determined in the interval 278 K - 363 K, for the reaction of t-Butyl with oxygen molecules in the interval 243 K - 363 K. The products of the reaction of t-Butyl with molecular oxygen are examined in a static photolysis cell with FTIR-detection. The kinetics of the reactions of the radicals t-Butyl, c-Heptyl, c-Heptyl, c-Octyl and 2-Chlor-2-Methyl-Propyl with ozone is determined at room temperature. The rate of the reactions of the radicals t-Butyl and Allyl with Nitrogen Monoxide is determined in the range 243 - 363 K. The kinetics of the reactions of the radicals Allyl, 2-Propyl, 2-Butyl, t-Butyl, c-Heptyl, c-Heptyl, c-Oktyl and 2-Chlor-2-Methyl-Propyl with Hydrogen atoms is determined at room temperature." @default.
• W2276249767 created "2016-06-24" @default.
• W2276249767 creator A5054467422 @default.
• W2276249767 date "2022-02-20" @default.
• W2276249767 modified "2023-09-25" @default.
• W2276249767 title "Erzeugung, Nachweis und Reaktionen reiner, teiloxidierter und substituierter Kohlenwasserstoffradikale in der Gasphase" @default.
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• W2276249767 doi "https://doi.org/10.53846/goediss-2137" @default.
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