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- W2276707934 abstract "Atoms of Cr, Mn, Fe, Co, Ni, and Cu formed by vacuum vaporization of the metals react with 2-nitropropane at −196°C. The products isolated at 0°C are new propane-2-nitronato complexes of the metals, different from those made by conventional metathesis reactions. Cr, Mn, and Fe form basic complexes [M{O2NC(CH3)2}20H] with additional H2O in the lattice, Co gives [Co{O2NC(CH3)2}2], and Cu thermally and air-sensitive [Cu4O{O2NC(CH3)2} 2]. Ni gives two propane-2-nitronato complexes, one of which contains coordinated NO. Reduction and rearrangements occur in the reactions of Mo and Ru atoms with 2-nitropropane. The results suggest that using high temperatures to form metal atoms may open a new chapter in “classical” coordination chemistry.Index EntriesTransition metal atoms, reactions with 2-nitropropane2-nitropropane, reactions with transition metal atomsmetals, reactions with 2-nitropropanechromium, reaction with 2-nitropropanemanganese, reaction with 2-nitropropaneiron, reaction with 2-nitropropanecobalt, reaction with 2-nitropropanenickel, reaction with 2-nitropropanecopper, reaction with 2-nitropropane" @default.
- W2276707934 created "2016-06-24" @default.
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- W2276707934 date "1984-01-01" @default.
- W2276707934 modified "2023-09-27" @default.
- W2276707934 title "Reactions of Transition Metal Atoms with 2-Nitropropane" @default.
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- W2276707934 doi "https://doi.org/10.1007/978-1-4612-5180-4_25" @default.
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