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- W2277230932 abstract "We report a new method for fabricating supramolecular polymers with controlled structure and molecular weight through reversible conformational modulation. To this end, the crown-ether-based taco complex was introduced. We prepared a monomer containing a bis(m-phenylene)-32-crown-10 in the core, which can supramolecularly polymerize efficiently in solution. When the conformation of the crown ether core was folded into a taco complex, the linear supramolecular polymerization could be significantly depressed, thus decreasing the molecular weight of the supramolecular polymer. In addition, extracting the depolymerizing agent with aqueous solution of cucurbit[7]uril could disassociate the taco complex and regenerate the supramolecular polymer with molecular weight as high as before. It is anticipated that this study can provide a facile and general methodology for controllable supramolecular polymerization." @default.
- W2277230932 created "2016-06-24" @default.
- W2277230932 creator A5028617332 @default.
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- W2277230932 date "2015-12-07" @default.
- W2277230932 modified "2023-10-16" @default.
- W2277230932 title "Supramolecular Polymerization Controlled by Reversible Conformational Modulation" @default.
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- W2277230932 doi "https://doi.org/10.1021/acsmacrolett.5b00831" @default.
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