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• W2277514575 abstract "Ethyl-adamantyl side groups substituted onto para-bis(2-thienyl)phenylene, a solid-state fluorescent dye, were found to induce π–π interactions between the conjugated para-bis(2-thienyl)phenylene cores. At the same time, stacking between the central unit and the adamantyl-containing side group was observed. As a result, due to steric hindrance augmentation of the solid-state, luminescence was observed. Moreover, substitution of standard alkyl side chains with ethyl-adamantyl groups resulted in raising the melting point temperature from 55 °C to ~250 °C. Aside from possible further-functionalization of the para-bis(2-thienyl)phenylene conjugated unit, aforesaid approach can be applied in a wide range of molecules and polymers, when luminescent properties and thermal stability can be tune through the side-chain engineering of organic materials." @default.
• W2277514575 created "2016-06-24" @default.
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• W2277514575 date "2016-07-01" @default.
• W2277514575 modified "2023-09-26" @default.
• W2277514575 title "Adamantyl side groups boosting the efficiency and thermal stability of organic solid-state fluorescent dyes" @default.
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• W2277514575 doi "https://doi.org/10.1016/j.jlumin.2016.02.019" @default.
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