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• W2277620580 abstract "Chemical sciences are on continuous evolution offering more and more complex synthetic strategies that rely on emerging inter- and trans-disciplinary vocation. In this tutorial review, we demonstrate how integrative chemistry, through combining soft matter and soft chemistry, allows positioning chemical reactors within the geometric space. Therefore, we focus the examples on biliquid foam oil/water interfaces and sol–gel chemistry. In this view we distinguish between diluted and concentrated emulsions, acting respectively as discrete chemical reactors and percolated ones. Along the manuscript, non-exhaustive morphosyntheses of advanced functional materials are proposed when dedicated either to heterogeneous biocatalysts, energy conversion systems and thermo-stimulated delivery of encapsulated substances. Les sciences chimiques sont en constante évolution, ce qui se traduit par des modes opératoires de plus en plus complexes à vocation inter- et transdisciplinaire. Dans cette revue, nous démontrons comment la chimie intégrative, en combinant matière molle et chimie douce, parvient à positionner les réacteurs chimiques dans l'espace géométrique. Ainsi, nous focalisons le propos sur les interfaces huile/eau d'émulsions et la chimie sol–gel. Dans cette optique, nous distinguons les émulsions diluées et concentrées, intervenant respectivement comme réacteurs chimiques discrétisés ou percolés. Dans cet article, nous donnons des exemples non exhaustifs de morphosynthèses de matériaux fonctionnels dédiés, par exemple, à la biocatalyse hétérogène, à la conversion d'énergie ou à la délivrance thermo-stimulée de substances encapsulées." @default.
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• W2277620580 date "2016-01-01" @default.
• W2277620580 modified "2023-10-07" @default.
• W2277620580 title "Integrative chemistry: Positioning chemical reactors within the geometric space as a tool for the design of advanced functional materials" @default.
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• W2277620580 doi "https://doi.org/10.1016/j.crci.2015.06.001" @default.
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