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• W2278487030 endingPage "10877" @default.
• W2278487030 startingPage "10871" @default.
• W2278487030 abstract "Herein, a sensitive fluorimetric assay for dissolved carbon dioxide (dCO2) was developed by using ion-induced self-assembly of a tetraphenylethylene derivative by taking advantage of its aggregation induced emission property. Chitosan, a commercially available polymer having amine functionality was utilized for the ion induced assay. In the presence of dCO2, the amine groups in the chitosan get protonated to convert neutral chitosan to a positively charged species, triggering negatively charged tetraphenylethene derivative (probe 1) to aggregate with it by electrostatic interaction. The aggregation causes intense blue fluorescence output from the system. The extent of the aggregation is reliant on the charge density of polymer, which is equivalent to dCO2 concentration. A linear relationship from 5 to 50 μM of dCO2, with a limit of detection of 5 × 10(-6) M (0.00127 hPa) was obtained. This is the first report for detecting dCO2 utilizing the AIE property." @default.
• W2278487030 created "2016-06-24" @default.
• W2278487030 creator A5013296362 @default.
• W2278487030 creator A5032387137 @default.
• W2278487030 creator A5047065306 @default.
• W2278487030 creator A5071528126 @default.
• W2278487030 creator A5072682334 @default.
• W2278487030 date "2015-10-26" @default.
• W2278487030 modified "2023-09-25" @default.
• W2278487030 title "Fluorescence Turn-on Chemosensor for the Detection of Dissolved CO₂ Based on Ion-Induced Aggregation of Tetraphenylethylene Derivative" @default.
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• W2278487030 doi "https://doi.org/10.1021/acs.analchem.5b02339" @default.
• W2278487030 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26458016" @default.
• W2278487030 hasPublicationYear "2015" @default.
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