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- W2278563841 endingPage "1193" @default.
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- W2278563841 abstract "The first copper-catalyzed asymmetric formal [4 + 2] cycloaddition of o-aminophenol derivatives with propargylic esters as the bis-electrophilic C2 synthons for the stereoselective construction of chiral 2,3,4-trisubstituted 2H-1,4-benzoxazines bearing an exocyclic double bond has been developed. By using a structurally modified chiral ketimine P,N,N-ligand, a wide range of optically active 2H-1,4-benzoxazines were prepared in high yields and with excellent enantioselectivities (up to 97% ee)." @default.
- W2278563841 created "2016-06-24" @default.
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- W2278563841 date "2016-02-23" @default.
- W2278563841 modified "2023-09-27" @default.
- W2278563841 title "Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of <i>o</i>-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2<i>H</i>-1,4-benzoxazines" @default.
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- W2278563841 doi "https://doi.org/10.1021/acs.orglett.6b00322" @default.
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