Matches in SemOpenAlex for { <https://semopenalex.org/work/W2279146593> ?p ?o ?g. }
- W2279146593 endingPage "2588" @default.
- W2279146593 startingPage "2581" @default.
- W2279146593 abstract "When equimolar solutions of the enantiomeric naphthalenediimide-based highly rigid triangles R-Δ and S-Δ in ClCH2CH2Cl are mixed, the racemate rac-Δ forms an organogel that is composed of interwoven fibers, resulting from the columnar stacking of the triangles in an alternating R-Δ/S-Δ fashion. Under identical conditions, the pure enantiomers do not form organogels. Density functional theory calculations reveal that the racemic RS dimer is more stable than the RR dimer as a result of the enantiomeric relationship between R-Δ and S-Δ, allowing them to act as two complementary rings comprised of 12 [C-H···O] interactions with an unprecedented and uninterrupted circular ADDAADDAADDA·DAADDAADDAAD alignment of hydrogen bond donors (D) and acceptors (A), in contrast with the square-wave manner in which the RR dimer forms a complementary yet interrupted ADADAD·DADADA circular sequence of six longer [C-H···O] hydrogen bonds. It follows that gelation is favored by weak interactions acting cooperatively in rings under precise stereoelectronic control." @default.
- W2279146593 created "2016-06-24" @default.
- W2279146593 creator A5001838489 @default.
- W2279146593 creator A5006843558 @default.
- W2279146593 creator A5013938837 @default.
- W2279146593 creator A5015629370 @default.
- W2279146593 creator A5021015026 @default.
- W2279146593 creator A5027688873 @default.
- W2279146593 creator A5055829204 @default.
- W2279146593 creator A5064735594 @default.
- W2279146593 creator A5067021218 @default.
- W2279146593 creator A5069579206 @default.
- W2279146593 creator A5088833974 @default.
- W2279146593 date "2016-03-09" @default.
- W2279146593 modified "2023-09-24" @default.
- W2279146593 title "Supramolecular Gelation of Rigid Triangular Macrocycles through Rings of Multiple C–H···O Interactions Acting Cooperatively" @default.
- W2279146593 cites W1964277385 @default.
- W2279146593 cites W1979757300 @default.
- W2279146593 cites W1980264932 @default.
- W2279146593 cites W1981174423 @default.
- W2279146593 cites W1981368803 @default.
- W2279146593 cites W1985717458 @default.
- W2279146593 cites W1986099885 @default.
- W2279146593 cites W1987790825 @default.
- W2279146593 cites W1989344736 @default.
- W2279146593 cites W1993766396 @default.
- W2279146593 cites W1993984194 @default.
- W2279146593 cites W1994486848 @default.
- W2279146593 cites W1998391934 @default.
- W2279146593 cites W2002363341 @default.
- W2279146593 cites W2006532602 @default.
- W2279146593 cites W2007421220 @default.
- W2279146593 cites W2010170568 @default.
- W2279146593 cites W2010947435 @default.
- W2279146593 cites W2012580767 @default.
- W2279146593 cites W2026172453 @default.
- W2279146593 cites W2027685213 @default.
- W2279146593 cites W2031687482 @default.
- W2279146593 cites W2032811669 @default.
- W2279146593 cites W2034128947 @default.
- W2279146593 cites W2040616652 @default.
- W2279146593 cites W2044591029 @default.
- W2279146593 cites W2047198164 @default.
- W2279146593 cites W2048221161 @default.
- W2279146593 cites W2050281276 @default.
- W2279146593 cites W2051727755 @default.
- W2279146593 cites W2052193935 @default.
- W2279146593 cites W2054493571 @default.
- W2279146593 cites W2055638156 @default.
- W2279146593 cites W2058090403 @default.
- W2279146593 cites W2062027124 @default.
- W2279146593 cites W2063444644 @default.
- W2279146593 cites W2066985414 @default.
- W2279146593 cites W2071360286 @default.
- W2279146593 cites W2073266977 @default.
- W2279146593 cites W2079547513 @default.
- W2279146593 cites W2081081773 @default.
- W2279146593 cites W2096941614 @default.
- W2279146593 cites W2105875419 @default.
- W2279146593 cites W2108806843 @default.
- W2279146593 cites W2112552355 @default.
- W2279146593 cites W2113280702 @default.
- W2279146593 cites W2122248295 @default.
- W2279146593 cites W2126838166 @default.
- W2279146593 cites W2127664681 @default.
- W2279146593 cites W2127909890 @default.
- W2279146593 cites W2137887694 @default.
- W2279146593 cites W2141009445 @default.
- W2279146593 cites W2141121631 @default.
- W2279146593 cites W2150932805 @default.
- W2279146593 cites W2152324904 @default.
- W2279146593 cites W2161174878 @default.
- W2279146593 cites W2163455478 @default.
- W2279146593 cites W2167883671 @default.
- W2279146593 cites W2254303632 @default.
- W2279146593 cites W2318636936 @default.
- W2279146593 cites W2319151201 @default.
- W2279146593 cites W2323988071 @default.
- W2279146593 cites W2329089387 @default.
- W2279146593 cites W2329363801 @default.
- W2279146593 cites W2330862899 @default.
- W2279146593 cites W2331883454 @default.
- W2279146593 cites W2333921307 @default.
- W2279146593 cites W2413880282 @default.
- W2279146593 doi "https://doi.org/10.1021/acs.joc.6b00281" @default.
- W2279146593 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26919158" @default.
- W2279146593 hasPublicationYear "2016" @default.
- W2279146593 type Work @default.
- W2279146593 sameAs 2279146593 @default.
- W2279146593 citedByCount "27" @default.
- W2279146593 countsByYear W22791465932016 @default.
- W2279146593 countsByYear W22791465932017 @default.
- W2279146593 countsByYear W22791465932018 @default.
- W2279146593 countsByYear W22791465932019 @default.
- W2279146593 countsByYear W22791465932020 @default.
- W2279146593 countsByYear W22791465932021 @default.
- W2279146593 countsByYear W22791465932022 @default.
- W2279146593 countsByYear W22791465932023 @default.