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- W2279428140 abstract "In this work,we report a new two-dimensional Sr(II) coordination polymer,namely,[Sr(L)(phen)(H2O)](1),based on 3,5-dinitro-salicylic acid(H2L) and 1,10-phenanthroline(phen).It crystallizes in monoclinic,space group P21/c with a = 15.479(3),b = 9.4020(19),c = 13.884(3) A,β= 103.76(3)°,V= 1962.5(7) A3,Z = 4,C19H12SrN4O8,Mr = 511.95,Dc = 1.733 g/cm3,F(000) =1024,μ(MoKα) = 2.805 mm-1,R = 0.0411 and wR = 0.1069.In 1,each L anion bridges three Sr(Ⅱ)atoms by using carboxylate and hydroxyl groups,yielding a two-dimensional layer structure.The phen ligands are alternately attached to both sides of the layer.The n-n stacking between L and phen in the same layer and hydrogen-bonding interactions between water molecule and carboxylate oxygen atom play an important role in stabilizing the layer structure of 1.The solid state luminescent property of 1 was also studied at room temperature." @default.
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- W2279428140 date "2015-01-01" @default.
- W2279428140 modified "2023-09-26" @default.
- W2279428140 title "Crystal Structure and Luminescence of a New Two-dimensional Sr(II) Coordination Polymer Based on 3,5-Dinitro-salicylic Acid and 1,10-Phenanthroline" @default.
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