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• W2279462462 abstract "In this work the phase transition of the system Niobium Hydrogen in thin films was investigated. The epitaxial Niobium films were fabricated using ion sputtering on sapphire substrates. The changes due to the hydrogen loading were observed with the scanning tunnel microscope (STM). With this method it is possible to detect the changes in the nanometer scale. With help of theoretical models it was possible to establish volume changes through the measured surface data. This is possible due to the linear relationship between hydrogen concentration and volume expansion. Comparisons between experimental data and calculations, which were done using the 'finite element method', allows to establish that the hydride precipitates are of cylindrical form. Thereafter the time continuously measurements of nuclei formation and precipitations growth was investigated. The growth is described through a 'Johnson-Mehl-Avrami' kinetic. Whereas coherent precipitations at first stage were observed, afterwards at higher Hydrogen concentration these transformed to incoherent. This coherent incoherent transition occur at precipitation sizes which shows a film thickness dependency." @default.
• W2279462462 created "2016-06-24" @default.
• W2279462462 creator A5016889495 @default.
• W2279462462 date "2022-02-20" @default.
• W2279462462 modified "2023-09-30" @default.
• W2279462462 title "Wasserstoffabsorption in epitaktischen Niobschichten: eine STM-Studie" @default.
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• W2279462462 doi "https://doi.org/10.53846/goediss-2713" @default.
• W2279462462 hasPublicationYear "2022" @default.
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