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- W2279566362 abstract "Previous chapters assert that a potential drop occurs over an EDL, consistent with the fact that chemical reactions occur at the surface to induce ionization of wall species. We now return to this subject in greater detail. Our goal is to be able to predict the equilibrium surface potential at microfluidic device interfaces as a function of the device material and solution conditions. This chapter frames the problem, describes associated parameters, and lists several models that can be used to attack this problem and interpret experimental data. We start by clarifying notation and terminology. We then discuss the chemical origins of surface charge for both Nernstian and non-Nernstian surfaces, discuss techniques for measuring and modifying electrokinetic potentials, and summarize observed zeta potentials for microfluidic substrates. Finally, we discuss how EDL theory is related to interpretation of zeta potential data and the relation between ζ and ϕ0." @default.
- W2279566362 created "2016-06-24" @default.
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- W2279566362 date "2012-06-05" @default.
- W2279566362 modified "2023-10-17" @default.
- W2279566362 title "Zeta Potential in Microchannels" @default.
- W2279566362 doi "https://doi.org/10.1017/cbo9780511760723.012" @default.
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