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• W2279649462 abstract "Multiply charged negative ions are seldom stable in the gas phase. Electrostatic repulsion leads either to autodetachment of electrons or fragmentation of the parent ion. With a binding energy of the second electron at 0.9 eV, B12H122− is a classic example of a stable dianion. It is shown here that ligand substitution can lead to unusually stable multiply charged anions. For example, dodecacyanododecaborate, B12(CN)122−, created by substituting H by CN is found to be highly stable with the second electron bound by 5.3 eV, which is six times larger than that in the B12H122−. Equally important is the observation that CB11(CN)122−, which contains one electron more than needed to satisfy the Wade-Mingos rule, is also stable with its second electron bound by 1.1 eV, while CB11H122− is unstable. The ability to stabilize multiply charged anions in the gas phase by ligand manipulation opens a new door for multiply charged species with potential applications as halogen-free electrolytes in ion batteries." @default.
• W2279649462 created "2016-06-24" @default.
• W2279649462 creator A5004635120 @default.
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• W2279649462 date "2016-02-16" @default.
• W2279649462 modified "2023-09-25" @default.
• W2279649462 title "Stability of B₁₂ (CN)₁₂ ²⁻ : Implications for Lithium and Magnesium Ion Batteries" @default.
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• W2279649462 doi "https://doi.org/10.1002/anie.201600275" @default.
• W2279649462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26880349" @default.
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