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- W2279917967 abstract "Abstract A new ruthenium (II) complex, of formula [Ru(NH3)5(NVF)](PF6)2, 1 (with NVF = N-vinylformamide) was synthesized and characterized by chemical analyses, spectroscopic and electrochemical techniques. The presence of two coordination sites within NVF makes complex 1 capable of showing a redox-dependent linkage isomerization process, which was detected by cyclic voltammetry and spectroelectrochemical measurements. Upon oxidation of the metallic center from Ru (II) to Ru (III) of complex 1 in N,N-dimethylformamide, linkage isomerization takes place from a vinyl-coordinated Ru(II) to an amide-coordinated Ru(III). This is an additional example of a system that can be applied in molecular memory devices or engines of a molecular machine." @default.
- W2279917967 created "2016-06-24" @default.
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- W2279917967 date "2016-04-01" @default.
- W2279917967 modified "2023-09-25" @default.
- W2279917967 title "Redox-induced linkage isomerization detected in [Ru(NH3)5(NVF)](PF6)2(NVF=N-vinylformamide)" @default.
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- W2279917967 doi "https://doi.org/10.1016/j.inoche.2016.02.015" @default.
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