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- W2279951804 abstract "A bis-cyclometalated iridium(III) complex with metal-centered chirality catalyzes the enantioselective transfer hydrogenation of ketones with high enantioselectivities at low catalyst loadings down to 0.002 mol%. Importantly, the rate of catalysis and enantioselectivity are markedly improved in the presence of a pyrazole co-ligand. The reaction is proposed to proceed via an iridium-hydride intermediate exploiting metal-ligand cooperativity (bifunctional catalysis)." @default.
- W2279951804 created "2016-06-24" @default.
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- W2279951804 date "2016-01-01" @default.
- W2279951804 modified "2023-09-23" @default.
- W2279951804 title "Chiral-at-metal iridium complex for efficient enantioselective transfer hydrogenation of ketones" @default.
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- W2279951804 doi "https://doi.org/10.1039/c6cc00972g" @default.
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